TALC

Talc is a mineral composed of hydrated magnesium silicate with the chemical formula H2Mg3(SiO3)4 or Mg3Si4O10(OH)2. In loose form, it is the widely used substance known as talcum powder. It occurs as foliated to fibrous masses, and in an exceptionally rare crystal form. It has a perfect basal cleavage, and the folia are non-elastic, although slightly flexible. It is the softest known mineral and listed as 1 on the Mohs hardness scale. It can be easily scratched by a fingernail. It is also sectile (can be cut with a knife). It has a specific gravity of 2.5–2.8, a clear or dusty luster, and is translucent to opaque. Talc is not soluble in water, but it is slightly soluble in dilute mineral acids. Its colour ranges from white to grey or green and it has a distinctly greasy feel. Its streak is white.

Soapstone is a metamorphic rock composed predominantly of talc.

Formation

Talc is a metamorphic mineral resulting from the metamorphism of magnesian minerals such as serpentine, pyroxene, amphibole, olivine, in the presence of carbon dioxide and water. This is known as talc carbonation or steatization and produces a suite of rocks known as talc carbonates.

Talc is primarily formed via hydration and carbonation via the following reaction;

serpentine + carbon dioxide → talc + magnesite + water
2 Mg3Si2O5(OH)4 + 3CO2 → Mg3Si4O10(OH)2 + 3 MgCO3 + 3 H2O

Talc can also be formed via a reaction between dolomite and silica, which is typical of skarnification of dolomites via silica-flooding in contact metamorphic aureoles;

dolomite + silica + water → talc + calcite + carbon dioxide
3 CaMg(CO3)2 + 4 SiO2 + H2O → Mg3Si4O10(OH)2 + 3 CaCO3 + 3 CO2

Talc can also be formed from magnesian chlorite and quartz in blueschist and eclogite metamorphism via the following metamorphic reaction:

chlorite + quartz → kyanite + talc + water

In this reaction, the ratio of talc and kyanite is dependent on aluminium content with more aluminous rocks favoring production of kyanite. This is typically associated with high-pressure, low-temperature minerals such as phengite, garnet, glaucophane within the lower blueschist facies. Such rocks are typically white, friable, and fibrous, and are known as whiteschist.

Talc is a tri-octahedral layered mineral; its structure is similar to that of pyrophyllite, but with magnesium in the octahedral sites of the composite layers.

Uses

Talc is used in many industries such as paper making, plastic, paint and coatings, rubber, food, electric cable, pharmaceuticals, cosmetics, ceramics, etc. A coarse grayish-green high-talc rock is soapstone or steatite and has been used for stoves, sinks, electrical switchboards, crayons, soap, etc. It is often used for surfaces of lab counter tops and electrical switchboards because of its resistance to heat, electricity and acids. Talc finds use as a cosmetic (talcum powder), as a lubricant, and as a filler in paper manufacture. Talc is used in baby powder, an astringent powder used for preventing rashes on the area covered by a diaper. It is also often used in basketball to keep a player’s hands dry. Most tailor’s chalk, or French chalk, is talc, as is the chalk often used for welding or metalworking.

Talc is also used as food additive or in pharmaceutical products as a glidant. In medicine talc is used as a pleurodesis agent to prevent recurrent pleural effusion or pneumothorax. In the European Union the additive number is E553b.

Talc is widely used in the ceramics industry in both bodies and glazes. In low-fire artware bodies it imparts whiteness and increases thermal expansion to resist crazing. In stonewares, small percentages of talc are used to flux the body and therefore improve strength and vitrification. It is a source of MgO flux in high temperature glazes (to control melting temperature). It is also employed as a matting agent in earthenware glazes and can be used to produce magnesia mattes at high temperatures.

Specifction

Grade A
Grade B
Grade C
Chemical Analysis
Elements
Result  %
SiO2
60 – 62
60 – 61
53 – 58
Al2O3
0. 3 – 0. 50
0. 5 – 1
1 – 2
Fe2O3
0.10 – 0.2
0. 4 – 0. 2
0. 7 – 0. 5
MnO
0. 01
0 . 01
0 . 01
MgO
31 – 32.5
30 – 31
28 – 30
L.O.I
4.5 -5.00
6. 5 – 5. 5
8 – 9
Mineralogical Analysis
Tale
> 90.0
>80. 0
chlorite
>8.00
<12. 00
carbonate
< 2.00
< 4. 00
Asbestos
Nil
Nil
Nil
Physical analysis
Whiteness – Z
90.00 ( min )
86. 00(min )
83. 0 (min )
SP. gr
0.55
0. 55
0. 55
pH
7.00
7. 20
7. 20